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Issue 19, 1993
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β,β-Dichlorovinyldiazonium or dichloro(diazomethyl)carbenium ion? Crystal structure and electron density distribution of β,β-dichlorovinyldiazonium hexachloroantimonate

Abstract

The crystal structure of β,β-dichlorovinyldiazonium hexachloroantimonate, 2·SbCl6, and the topological electron density analysis of 2 provide compelling evidence for the importance of chlorine-stabilized carbenium ion resonance forms for the stabilization of vinyldiazonium ions by β-substitution.

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Article type: Paper
DOI: 10.1039/C39930001530
Citation: J. Chem. Soc., Chem. Commun., 1993,0, 1530-1532
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    β,β-Dichlorovinyldiazonium or dichloro(diazomethyl)carbenium ion? Crystal structure and electron density distribution of β,β-dichlorovinyldiazonium hexachloroantimonate

    G. S. Chen, R. Glaser and C. L. Barnes, J. Chem. Soc., Chem. Commun., 1993, 0, 1530
    DOI: 10.1039/C39930001530

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