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Issue 16, 1993
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Molecular aluminium trihydride, AlH3: generation in a solid noble gas matrix and characterisation by its infrared spectrum and Ab initio calculations

Abstract

Broad-band photolysis of a solid noble gas matrix containing Al atoms and H2 gives rise to the planar, monomericAlH3 molecule, isotopically natural and deuteriated forms of which have been characterised by their IR spectra; confirmation is afforded by the results of MP2 ab initio and normal coordinate analysis calculations.

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Article type: Paper
DOI: 10.1039/C39930001302
Citation: J. Chem. Soc., Chem. Commun., 1993,0, 1302-1304
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    Molecular aluminium trihydride, AlH3: generation in a solid noble gas matrix and characterisation by its infrared spectrum and Ab initio calculations

    F. A. Kurth, R. A. Eberlein, H. Schnöckel, A. J. Downs and C. R. Pulham, J. Chem. Soc., Chem. Commun., 1993, 0, 1302
    DOI: 10.1039/C39930001302

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