The synthesis and conformational analysis of a pair of diastereoisomeric cyclic peptides with cis and transamide bonds, respectively

Sabrina Cumberbatch; Michael North; Guiseppe Zagotto

doi:10.1039/C39930000641

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The synthesis and conformational analysis of a pair of diastereoisomeric cyclic peptides with cis and transamide bonds, respectively

Sabrina Cumberbatch, Michael North and Guiseppe Zagotto

J. Chem. Soc., Chem. Commun., 1993, 641-642

DOI: 10.1039/C39930000641

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N-Protected, conformationally constrained, eight-membered ring containing cyclic dipeptides derived from methyl cyclo-[(R)-cysteinyl-(R)-penicillamine] contain a cis amide bond, whilst the corresponding peptides derved from cyclo-[(R)-cysteinyl-(S)-penicillamine] contain a trans amide bond.

Journal of the Chemical Society, Chemical Communications

The synthesis and conformational analysis of a pair of diastereoisomeric cyclic peptides with cis and transamide bonds, respectively

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