Initiated tert-butyl hydroperoxide-loaded low-temperature autoxidation of alkenes: alternative hydroperoxide syntheses and the preparation of a complete set of reference materials
Abstract
A complete set of characterization data for the allylic hydroperoxides prepared from 1-methylcyclohexene and the isomeric 4-methyloct-4-enes is presented. The data relies upon the preparation of allylic hydroperoxides by tert-butyl hydroperoxide-loaded autoxidations, singlet-ene oxidations and nucleo-philic substitution reactions. Appropriate allylic alcohols and relevant scission products have been prepared to support the assignments given.