Near-edge X-ray absorption spectroscopy (XAS) measurements for BaPb1 –xBixO3 have been made across the entire solid-solution range at the Bi LIII and Pb LIII absorption edges. By the use of appropriate standards, we infer that whereas the Pb valency in the material remains ‘PbIV-like’, the Bi valency increases as lead is doped into BaBiO3.
W. R. Flavell, B. C. Morris, I. Tweddell, D. Purdie, G. Thornton, P. L. Wincott and R. L. Bilsborrow, J. Mater. Chem., 1992, 2, 1209 DOI: 10.1039/JM9920201209
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