A Kinetic study of the very low pressure thermolysis of phenylacetic acid above 900 K reveals that its decomposition occurs in a concerted manner, yielding toluene and carbon dioxide, probably via a four-centre transition state [reaction (1)] [graphic omitted] with log[k∞(1)/s–1]=[(13 ± 0.3)–(12 200 ± 500)]/T.
A. J. Colussi, V. T. Amorebieta and M. A. Grela, J. Chem. Soc., Faraday Trans., 1992, 88, 2125 DOI: 10.1039/FT9928802125
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