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Issue 3, 1992
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Metal K-edge extended X-ray absorption fine structure studies of MoF6, RuF6, RhF6 and related fluoroanions

Abstract

Metal K-edge extended X-ray absorption fine structure data obtained for MoF6, RuF6 and RhF6 as solids at 10 K have been refined to give d(M–F)= 1.81 (Mo), 1.83 (Ru) and 1.84 Å(Rh). Corresponding values for the powdered fluoroanions at room temperature are ca. 1.85 Å for K[MF6](M = Ru or Rh) and 1.90–1.93 Å for K2[MF6](M = Ru, Rh or Pd). The value of d(Rh–Cl) in Cs2[RhCl6] is 2.31 Å. The results are compared with previous data on the 5d analogues and with X-ray crystallographic data.

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Article type: Paper
DOI: 10.1039/DT9920000447
Citation: J. Chem. Soc., Dalton Trans., 1992,0, 447-449
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    Metal K-edge extended X-ray absorption fine structure studies of MoF6, RuF6, RhF6 and related fluoroanions

    A. K. Brisdon, J. H. Holloway, E. G. Hope, W. Levason, J. S. Ogden and A. K. Saad, J. Chem. Soc., Dalton Trans., 1992, 0, 447
    DOI: 10.1039/DT9920000447

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