Novel structures of a trans-cyclooctene and trans-fused cyclopropane generated via photoisomerization of a gem-dichlorocyclopropyl-benzocycloheptenone

John L. Wood; Patrick J. Carroll; Amos B. Smith

doi:10.1039/C39920001433

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Journal of the Chemical Society, Chemical Communications

Issue 19, 1992

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Novel structures of a trans-cyclooctene and trans-fused cyclopropane generated via photoisomerization of a gem-dichlorocyclopropyl-benzocycloheptenone

John L. Wood , Patrick J. Carroll and Amos B. Smith

J. Chem. Soc., Chem. Commun., 1992, 1433-1434

DOI: 10.1039/C39920001433

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Abstract
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Photoisomerization of the gem-dichlorobenzobicyclo[5.1.0]octenone 1(6 h, Pyrex) furnished the trans-fused cyclopropane 2 and the trans- and cis-cyclooctenes 3 and 4; single-crystal X-ray analyses defined the novel photoproduct structures.

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Journal of the Chemical Society, Chemical Communications

Novel structures of a trans-cyclooctene and trans-fused cyclopropane generated via photoisomerization of a gem-dichlorocyclopropyl-benzocycloheptenone

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