Issue 17, 1992

Ruthenium(IV) silyl hydride complexes via reaction of silanes with 16-electron [Ru(η5-C5Me5)(PPri3)X](X = Cl, CH2SiHPh2, SiMePh2) complexes. Hydride migrations to an η2-silene ligand

Abstract

Reactions of [Ru(η5-C5Me5)(PPri3)(H)(η2-CH2[double bond, length half m-dash]SiPh2)] with hydrosilanes occur via initial migration of hydride to the silene ligand, and eventually give disilyl hydride or silyl dihydride ruthenium(IV) complexes; the 16-electron chloride[Ru(η5-C5Me5)(PPri3)Cl] adds mesityl (Mes) silane to give [Ru(η5-C5Me5)(PPri3)(H)2(SiHcMes)] which was crystallographically characterized.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1201-1203

Ruthenium(IV) silyl hydride complexes via reaction of silanes with 16-electron [Ru(η5-C5Me5)(PPri3)X](X = Cl, CH2SiHPh2, SiMePh2) complexes. Hydride migrations to an η2-silene ligand

B. K. Campion, R. H. Heyn and T. D. Tilley, J. Chem. Soc., Chem. Commun., 1992, 1201 DOI: 10.1039/C39920001201

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