The synthesis and isomerism of the first tris-chelated low-spin MnIII(1a) and MnII(1b) pair of complexes [MnL3]0,–, of the 4-chloro-o-benzoquinone oxime ligand HL is described; MnL3 has strong preference for mer-geometry but mer- and fac-isomers coexist in solution as well as in the crystal lattice of the [Et4N]+ salt of [MnL3]–.
P. Basu and A. Chakravorty, J. Chem. Soc., Chem. Commun., 1992, 809 DOI: 10.1039/C39920000809
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