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Issue 9, 1992
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The first molecular electronic hyperpolarizabilities of highly polarizable organic molecules: 2,6-di-tert-butylindoanilines

Abstract

The first molecular hyperpolarizabilities (β) of a series of 2,6-di-tert-butylindoanilines, measured by electric-field-induced second harmonic generation are somewhat more sensitive to donor strength than was found for analogously substituted nitrostilbenes, and dimethylindoaniline has a β roughly twice that of its 2,6 di-tert-butylated analogue, measured in chloroform; solvatochromic measurements on the former compound suggest that this decrease in hyperpolarizability is consistent with a bound-solvent effect.

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Article type: Paper
DOI: 10.1039/C39920000672
Citation: J. Chem. Soc., Chem. Commun., 1992, 672-674
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    The first molecular electronic hyperpolarizabilities of highly polarizable organic molecules: 2,6-di-tert-butylindoanilines

    S. R. Marder, L. Cheng and B. G. Tiemann, J. Chem. Soc., Chem. Commun., 1992, 672
    DOI: 10.1039/C39920000672

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