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Issue 18, 1992
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Boride cluster fusion via an M4-unit (M = Cu or Ag): molecular structure of [ppn][{Ru4H(CO)12B}2Cu4(µ-Cl)][Cl][ppn =(PPh3)2N]

Abstract

The reaction of [ppn][Ru4H(CO)12BH] with [Cu(MeCN)4][BF4] in the presence of [ppn][Cl] yields [ppn][{Ru4H(CO)12B}2-Cu4(µ-Cl)][Cl], which has been structurally characterised; the introduction of silver in place of copper yields [ppn][{Ru4H(CO)12BH}2Ag] in addition to [ppn][{Ru4H(CO)12B}2Ag4(µ-Cl)][Cl].

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Article type: Paper
DOI: 10.1039/C39920001365
Citation: J. Chem. Soc., Chem. Commun., 1992,0, 1365-1367
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    Boride cluster fusion via an M4-unit (M = Cu or Ag): molecular structure of [ppn][{Ru4H(CO)12B}2Cu4(µ-Cl)][Cl][ppn =(PPh3)2N]

    S. M. Draper, A. D. Hattersley, C. E. Housecroft and A. L. Rheingold, J. Chem. Soc., Chem. Commun., 1992, 0, 1365
    DOI: 10.1039/C39920001365

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