By the isolation and kinetic studies of an adduct (cis-1,4-dihydro-1-nitro-4-trinitromethylnaphthalene) from the photolysis of naphthalene–tetranitromethane in dichloromethane or acetonitrile, it is shown that the route to nitro substitution products proceeds via addition–elimination, the latter step being either thermal or base-catalysed.
L. Eberson, M. P. Hartshorn, F. Radner and W. T. Robinson, J. Chem. Soc., Chem. Commun., 1992, 566 DOI: 10.1039/C39920000566
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