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Issue 7, 1992
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The effect of bending modes on the intramolecular electron-transfer rates of mixed-valence 1′,3′,1‴,3‴-tetraethyl- and 1′,2′,1‴,2‴-tetraethyl-biferrocenium triiodides

Teng-Yuan Dong,  Chung-Kay Chang,  Chun-Hsun Huang,  Yuh-Sheng Wen,  Shyi-Long Lee,  Jing-An Chen,  Wen-Yann Yeh  and  Andrew Yeh 

Abstract

The results of an X-ray structure determination of 1′,3′,1‴,3‴-tetraethylbiferrocenium triiodide, the effects of changing the relative positions of ethyl substituents from 1′,3′,1‴,3‴ to 1′,2′,1‴,2‴ on the intramolecular electron-transfer rates of biferrocenium salts in the solid state, and a theoretical explanation of the influence of steric factors on the electron-transfer rates are reported.

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Article type: Paper
DOI: 10.1039/C39920000526
Citation: J. Chem. Soc., Chem. Commun., 1992,0, 526-528
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    The effect of bending modes on the intramolecular electron-transfer rates of mixed-valence 1′,3′,1‴,3‴-tetraethyl- and 1′,2′,1‴,2‴-tetraethyl-biferrocenium triiodides

    T. Dong, C. Chang, C. Huang, Y. Wen, S. Lee, J. Chen, W. Yeh and A. Yeh, J. Chem. Soc., Chem. Commun., 1992, 0, 526
    DOI: 10.1039/C39920000526

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