The Sharpless oxidation of o-nitrophenyl vinyl selenides affords chiral allenes via asymmetric selenoxide elimination in moderate enantiomeric excess and in a good chemical yield.
N. Komatsu, Y. Nishibayashi, T. Sugita and S. Uemura, J. Chem. Soc., Chem. Commun., 1992, 46 DOI: 10.1039/C39920000046
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