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Issue 18, 1991
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Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K

Abstract

The standard molar Gibbs free energies of hydration, ΔhydG°, of 109 (mainly inorganic) ions ranging in their charges from –3 to +4 have been compiled and interpreted in terms of a model used previously for other thermodynamic quantities of hydration. The main contributions to ΔhydG° are the electrostatic effects, resulting in solvent immobilization, electrostriction, and dielectric saturation in a hydration shell of specified thickness, and further such effects on the water that surrounds this shell. Other effects contribute to ΔhydG° to a minor extent only.

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Article type: Paper
DOI: 10.1039/FT9918702995
Citation: J. Chem. Soc., Faraday Trans., 1991,87, 2995-2999
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    Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K

    Y. Marcus, J. Chem. Soc., Faraday Trans., 1991, 87, 2995
    DOI: 10.1039/FT9918702995

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