Jump to main content
Jump to site search

Issue 11, 1991
Previous Article Next Article

Ultraviolet–visible spectroscopic studies on manganese and rhenium oxide fluorides in low-temperature matrices

Abstract

Five high-oxidation-state metal oxide fluorides, MnO3F, ReO3F, ReO2F3, ReOF5 and ReOF4 have been isolated as molecular species in inert-gas matrices at low temperatures, and studied by IR and UV/VIS spectroscopy. In particular, the electronic spectra are described and the principal charge-transfer bands assigned using the optical electronegativity model. This suggested that a new value for χopt(F) of 3.6 is appropriate for transition-metal oxide fluorides.

Back to tab navigation

Article type: Paper
DOI: 10.1039/DT9910003127
Citation: J. Chem. Soc., Dalton Trans., 1991,0, 3127-3132
  •   Request permissions

    Ultraviolet–visible spectroscopic studies on manganese and rhenium oxide fluorides in low-temperature matrices

    A. K. Brisdon, J. H. Holloway, E. G. Hope, P. J. Townson, W. Levason and J. S. Ogden, J. Chem. Soc., Dalton Trans., 1991, 0, 3127
    DOI: 10.1039/DT9910003127

Search articles by author

Spotlight

Advertisements