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Issue 21, 1991
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A new diphenylantimony oxide containing a planar Sb6O6 ring

I. Gary Southerington,  Michael J. Begley  and  D. Bryan Sowerby 

Abstract

Treatment of diphenylantimony bromide oxide, (Ph2SbBrO)2, with silver oxalate leads to a novel ionic product, containing a planar twelve-membered cyclic antimony–oxygen dication in which two pairs of adjacent antimony atoms are further linked by hydroxy bridges to give Sb2O2 rings and a quadridentate oxalate is coordinated between the two remaining antimony atoms of the ring; the counter ions are two cis-dioxalatodiphenylantimony anions.

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Article type: Paper
DOI: 10.1039/C39910001555
Citation: J. Chem. Soc., Chem. Commun., 1991,0, 1555-1556
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    A new diphenylantimony oxide containing a planar Sb6O6 ring

    I. G. Southerington, M. J. Begley and D. B. Sowerby, J. Chem. Soc., Chem. Commun., 1991, 0, 1555
    DOI: 10.1039/C39910001555

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