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Issue 8, 1991
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Unexpected formation of 5,12-dimethyl-3,7,10,14,15,16-tetraazapentacyclo[7.5.1.12,8.15,16.112,15]octadecane, a novel caged nitrogen heterocycle, and preparation and X-ray crystal structure of its copper(II)chloride complex

Abstract

1,1,1-Tris(aminomethyl)ethane 2 is shown to condense with glyoxal in methanaol, in the absence of metal ions, to give a novel caged nitrogen heterocycle 3 whose structure has been confirmed by spectral data and through X-ray crystallographic analysis of its copper(II) chloride complex 5.

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Article type: Paper
DOI: 10.1039/C39910000607
Citation: J. Chem. Soc., Chem. Commun., 1991,0, 607-608
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    Unexpected formation of 5,12-dimethyl-3,7,10,14,15,16-tetraazapentacyclo[7.5.1.12,8.15,16.112,15]octadecane, a novel caged nitrogen heterocycle, and preparation and X-ray crystal structure of its copper(II)chloride complex

    D. C. Craig, M. Kassiou and R. W. Read, J. Chem. Soc., Chem. Commun., 1991, 0, 607
    DOI: 10.1039/C39910000607

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