Issue 1, 1990

Biosynthesis of isofucosterol from [2-13C2H3]acetate and [1,2-13C2]acetate in tissue cultures of Physalis peruviana—the stereochemistry of the hydride shift from C-24 to C-25

Abstract

Migration of the hydrogen atom at C-24 of cycloartenol to C-25 from the Re-face of the double bond occurred in the biosynthesis of isofucosterol in cell cultures of Physalis peruviana fed [2-13C2H3]acetate and [1,2-13C2] acetate. This was verified by 13C n.m.r. spectroscopy.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1990, 105-109

Biosynthesis of isofucosterol from [2-13C2H3]acetate and [1,2-13C2]acetate in tissue cultures of Physalis peruviana—the stereochemistry of the hydride shift from C-24 to C-25

S. Seo, A. Uomori, Y. Yoshimura, H. Seto, Y. Ebizuka, H. Noguchi, U. Sankawa and K. Takeda, J. Chem. Soc., Perkin Trans. 1, 1990, 105 DOI: 10.1039/P19900000105

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