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Issue 3, 1990
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Spectroscopic studies on the hexafluorides of ruthenium and rhodium isolated in low-temperature matrices

Abstract

New syntheses of RuF6 and RhF6 are reported involving fluorination of the corresponding pentafluorides at 220 °C and 30 atm. Infra-red spectra for RuF6 and RhF6 isolated in nitrogen and argon matrices at 12 K have been recorded and assigned. The u.v.–visible spectra in nitrogen matrices are complex containing both fluorine-to-metal charge-transfer and dd transitions. Assignments for the main features are proposed.

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Article type: Paper
DOI: 10.1039/DT9900000715
Citation: J. Chem. Soc., Dalton Trans., 1990,0, 715-718
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    Spectroscopic studies on the hexafluorides of ruthenium and rhodium isolated in low-temperature matrices

    A. K. Brisdon, P. J. Jones, W. Levason, J. S. Ogden, J. H. Holloway, E. G. Hope and G. Stanger, J. Chem. Soc., Dalton Trans., 1990, 0, 715
    DOI: 10.1039/DT9900000715

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