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Issue 14, 1990
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The effect of strain on the catalytic reactions of bridged thiazolium salts as models of thiamin

Abstract

The reactivity of bridged thiazolium salts (9) and (10) has been studied; the model (9) with the shorter bridge is unable to catalyse the benzoin condensation reaction and it was shown that this is due to failure of the condensation step (5)→(6), probably owing to the effects of strain.

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Article type: Paper
DOI: 10.1039/C39900000961
Citation: J. Chem. Soc., Chem. Commun., 1990,0, 961-963
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    The effect of strain on the catalytic reactions of bridged thiazolium salts as models of thiamin

    F. J. Leeper and D. H. C. Smith, J. Chem. Soc., Chem. Commun., 1990, 0, 961
    DOI: 10.1039/C39900000961

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