Polyoxyethylene–polyoxypropylene block copolymers: a novel phase transition in aqueous solutions of pluronic F87 (poloxamer 237)

Neil Mitchard; Anthony Beezer; Nicolas Rees; John Mitchell; Stephen Leharne; Babur Chowdhry; Graham Buckton

doi:10.1039/C39900000900

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Journal of the Chemical Society, Chemical Communications

Issue 13, 1990

Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

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Polyoxyethylene–polyoxypropylene block copolymers: a novel phase transition in aqueous solutions of pluronic F87 (poloxamer 237)

Neil Mitchard, Anthony Beezer, Nicolas Rees, John Mitchell, Stephen Leharne, Babur Chowdhry and Graham Buckton

J. Chem. Soc., Chem. Commun., 1990, 900-901

DOI: 10.1039/C39900000900

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Abstract
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An unexpected phase transition in dilute aqueous solution of the nonionic surfactant poloxamer P237 (Pluronic F87), with an excess specific heat capacity maximum at 307.7 K in the concentration range 1–10 mg/ml, has been observed using high sensitivity differential scanning calorimetry (HSDSC); the thermodynamic parameters associated with this transition are reported.

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Neil Mitchard
Anthony Beezer
Nicolas Rees
John Mitchell
Stephen Leharne
Babur Chowdhry
Graham Buckton

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Journal of the Chemical Society, Chemical Communications

Polyoxyethylene–polyoxypropylene block copolymers: a novel phase transition in aqueous solutions of pluronic F87 (poloxamer 237)

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Journal of the Chemical Society, Chemical Communications

Polyoxyethylene–polyoxypropylene block copolymers: a novel phase transition in aqueous solutions of pluronic F87 (poloxamer 237)

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