Issue 22, 1990

A novel zwitterionic ortho-metallated ruthenium(II) phenolate

Abstract

Decarbonylative metallation of the dialdehyde 2b by [Ru(PPh3)3Cl2] affords the unusual complex [Ru(MeL)(CO)(PPh3)2(Cl)]4 which has been characterised by X-ray crystallography and in which the RuIIP2C2ClO coordination unit bears a single net negative charge; the Ru(MeL)(3, R = Me) fragment incorporates a four-membered C,O-chelated phenolato function with a neighbouring monoprotonated azomethine moiety.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1626-1627

A novel zwitterionic ortho-metallated ruthenium(II) phenolate

N. Bag, S. B. Choudhury, G. K. Lahiri and A. Chakravorty, J. Chem. Soc., Chem. Commun., 1990, 1626 DOI: 10.1039/C39900001626

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements