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Issue 3, 1989
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Heat of solution and electric conductivity of electrolytes in water–tetrahydrofuran mixtures

Stefania Taniewska-Osińska,  Zygmunt Kozłowski,  Bożena Nowicka,  Adam Bald  and  Adam Szejgis 

Abstract

Integral heats of solution of sodium perchlorate (NaClO4) in water–tetrahydrofuran (THF) mixtures from 0 to 100 mol% THF have been measured. The electric conductivity of NaClO4 solutions in binary solvents containing from 0 to 80 mol% THF have also been measured, as have the conductivities of solutions of sodium chloride (NaCl) and sodium iodide (NaI) in mixtures containing from 0 to 35 mol% THF. Molar electro-conductivities, Walden products and association equilibria constants have been determined. Taking into account ion-pair association, standard enthalpies of solution have been recalculated.

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Article type: Paper
DOI: 10.1039/F19898500479
Citation: J. Chem. Soc., Faraday Trans. 1, 1989,85, 479-483
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    Heat of solution and electric conductivity of electrolytes in water–tetrahydrofuran mixtures

    S. Taniewska-Osińska, Z. Kozłowski, B. Nowicka, A. Bald and A. Szejgis, J. Chem. Soc., Faraday Trans. 1, 1989, 85, 479
    DOI: 10.1039/F19898500479

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