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Issue 11, 1989
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Tris(ethylenediamine)zinc(II) fluoride dihydrate: X-ray structure reveals a strongly hydrogen bonded difluoride cluster, [F2(H2O)2]2–

Abstract

The crystal structure of the title compound shows it to contain the first example of a di-anion cluster, [F2(H2O)2]2–, in which two fluoride ions and two water molecules form a diamond shaped array with strong hydrogen bonds of R(O ⋯ F) 2.63 Å(av.).

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Article type: Paper
DOI: 10.1039/C39890000738
Citation: J. Chem. Soc., Chem. Commun., 1989,0, 738-739
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    Tris(ethylenediamine)zinc(II) fluoride dihydrate: X-ray structure reveals a strongly hydrogen bonded difluoride cluster, [F2(H2O)2]2–

    J. Emsley, M. Arif, P. A. Bates and M. B. Hursthouse, J. Chem. Soc., Chem. Commun., 1989, 0, 738
    DOI: 10.1039/C39890000738

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