(±)-[5-13C]Faktor-1 ester is synthesised following an east–west disconnection strategy and is used to show by specific enzymic incorporation experiments that the first C-methylation product, precorrin-1, on the B12-biosynthetic pathway is a tetrahydrochlorin.
R. D. Brunt, F. J. Leeper, I. Grgurina and A. R. Battersby, J. Chem. Soc., Chem. Commun., 1989, 428 DOI: 10.1039/C39890000428
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