Manganese clusters, Mn3–4O1–2LxLy(Lx= RCO2–; Ly= pyridine or 2,2′-bipyridine), are novel catalysts that can convert C–H bonds to C–OH bonds in C2, C3, and cyclo-C6 hydrocarbons in the presence of t-butyl hydroperoxide as the mono-oxygen transfer reagent.
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