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Issue 20, 1988
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X-Ray structures of [Cu(cyclam)(H2O)2]F2·4H2O (cyclam = 1,4,8,11-tetra-azacyclotetradecane) and [Cu(en)2(H2O)2]F2·4H2O (en = ethylenediamine) reveal [F(H2O)4] with strong hydrogen bonds

Abstract

The much-discussed hydrated fluoride ion [F(H2O)4] has turned up in two copper complexes whose structures shows this ion to have four short hydrogen bonds with r(O ⋯ F)= 2.65 Å(av.).

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Article type: Paper
DOI: 10.1039/C39880001387
Citation: J. Chem. Soc., Chem. Commun., 1988,0, 1387-1388
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    X-Ray structures of [Cu(cyclam)(H2O)2]F2·4H2O (cyclam = 1,4,8,11-tetra-azacyclotetradecane) and [Cu(en)2(H2O)2]F2·4H2O (en = ethylenediamine) reveal [F(H2O)4] with strong hydrogen bonds

    J. Emsley, M. Arif, P. A. Bates and M. B. Hursthouse, J. Chem. Soc., Chem. Commun., 1988, 0, 1387
    DOI: 10.1039/C39880001387

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