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Issue 20, 1988
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Studies of the chemical oxidation of the iron(II) complex of N-methyltetraphenylporphyrin to form the corresponding symmetrical and unsymmetrical µ-oxo di-iron complexes

Abstract

New µ-oxo di-iron N-methyltetraphenylporphyrin (MeTPP) species of formula [{(MeTPP)Fe}2O](ClO4)2 and [(MeTPP)Fe–O–Fe(TPP)]ClO4 have been prepared by the reaction of (MeTPP)FeCl with silver perchlorate and characterized by i.r., visible, n.m.r., and Mössbauer spectroscopy and electrochemical measurements; the mechanism of formation of the di-iron complexes is briefly discussed.

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Article type: Paper
DOI: 10.1039/C39880001377
Citation: J. Chem. Soc., Chem. Commun., 1988, 1377-1378
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    Studies of the chemical oxidation of the iron(II) complex of N-methyltetraphenylporphyrin to form the corresponding symmetrical and unsymmetrical µ-oxo di-iron complexes

    A. Wysłouch, L. Latos-Grażyński, M. Grzeszczuk, K. Drabent and T. Bartczak, J. Chem. Soc., Chem. Commun., 1988, 1377
    DOI: 10.1039/C39880001377

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