In general, decamethylsilicocene (1) reacts with Brønsted acids under oxidative addition yielding SiIV compounds of the type (Me5C5)2Si(H)X (2)–(7); as an exception, the cyclotetrasilane (Me5C5SiF)4(8) is formed in the reaction with tetrafluoroboric acid and has been characterized by an X-ray diffraction study.
P. Jutzi, U. Holtmann, H. Bögge and A. Müller, J. Chem. Soc., Chem. Commun., 1988, 305 DOI: 10.1039/C39880000305
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