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Issue 0, 1987
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Synthesis and electrochemical properties of some metallated and peripherally substituted porphyrin co-facial dimers

James A. Cowan  and  Jeremy K. M. Sanders 

Abstract

The high dilution coupling of mesoporphyrin-II bis(acid chloride) with a diol derived from mesoporphyrin-II bis(methyl ester) yields two diastereoisomers of a co-facial porphyrin dimer. The use of zinc as a removable protecting group for the diol face gives access to a wide range of mixed metal and mixed valence co-facial porphyrin dimers.Introduction of ami and nitro peripheral substituents provides another method for altering independenty the properties of each of the prophyrin faces in a dimer.

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Article type: Paper
DOI: 10.1039/P19870002395
Citation: J. Chem. Soc., Perkin Trans. 1, 1987,0, 2395-2402
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    Synthesis and electrochemical properties of some metallated and peripherally substituted porphyrin co-facial dimers

    J. A. Cowan and J. K. M. Sanders, J. Chem. Soc., Perkin Trans. 1, 1987, 0, 2395
    DOI: 10.1039/P19870002395

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