SCHEDULED MAINTENANCE
Hypervalent iodine oxidation of various silyl enol ethers (aromatic, heteroaromatic, and aliphatic) using iodosobenzene–boron trifluoride diethyl ether–water provides a general and direct route for the α-hydroxylation of ketones. The structures of 2-hydroxy-(8) and 3-hydroxy-acetylpyridine (9) are discussed as well as the scope and mechanism of the reaction.
R. M. Moriarty, M. P. Duncan and O. Prakash, J. Chem. Soc., Perkin Trans. 1, 1987, 1781 DOI: 10.1039/P19870001781
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