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Issue 6, 1987
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Application of the perturbed-elastic-rod model to the longitudinal acoustical modes of poly(oxyethylene)s and their n-hexadecyl ethers

Abstract

The LAM-1 frequencies of low-molecular-weight poly(oxyethylene) dimethyl and diethyl ethers and methyl-n-hexadecyl ethers are interpreted by modelling the chain molecules as elastic rods perturbed by end masses and end forces. In the case of the n-hexadecyl ethers the important factor is the damping effect of the alkyl block acting as an inertial mass.

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Article type: Paper
DOI: 10.1039/F29878300927
Citation: J. Chem. Soc., Faraday Trans. 2, 1987,83, 927-932
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    Application of the perturbed-elastic-rod model to the longitudinal acoustical modes of poly(oxyethylene)s and their n-hexadecyl ethers

    F. Viras, K. Viras, C. Campbell, T. A. King and C. Booth, J. Chem. Soc., Faraday Trans. 2, 1987, 83, 927
    DOI: 10.1039/F29878300927

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