Issue 1, 1987

Structure and bonding in (R2SiX)2 molecules (X = O, NH, CH2, or S; R = H)

Abstract

Analysis of the structure and bonding in (R2SiX)2 molecules (X = O, NH, CH2, or S; R = H) by empirical, MNDO, and ab initio molecular orbital methods shows that: (a) the electronic structures of these systems are qualitatively similar, (b) short non- bonded 1,3-Si–Si distances are predominantly determined by the Si–X distance, and (c) the small antibonding Si–Si interactions increase with increasing Si–Si distance.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1987, 271-273

Structure and bonding in (R2SiX)2 molecules (X = O, NH, CH2, or S; R = H)

E. D. Jemmis, P. N. V. P. Kumar and N. R. S. Kumar, J. Chem. Soc., Dalton Trans., 1987, 271 DOI: 10.1039/DT9870000271

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