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Issue 6, 1987
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Pyrolysis of bicyclo[2.2.1]heptane-2-thiols: evidence for a carbene intermediate in a thermal hydrogen sulphide elimination

Abstract

Pyrolysis of endo- and exo-bicyclo[2.2.1]heptane-2-thiols yields tricyclo[2.2.1.02,6]heptane and bicyclo[2.2.1]hept-2-ene via competing carbene and radical mechanisms.

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Article type: Paper
DOI: 10.1039/C39870000416
Citation: J. Chem. Soc., Chem. Commun., 1987,0, 416-417
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    Pyrolysis of bicyclo[2.2.1]heptane-2-thiols: evidence for a carbene intermediate in a thermal hydrogen sulphide elimination

    D. E. Johnson and A. F. Dimian, J. Chem. Soc., Chem. Commun., 1987, 0, 416
    DOI: 10.1039/C39870000416

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