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Issue 5, 1987
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Evidence for a strong labilization effect by co-ordinated sulphite in amine complexes of palladium(II)

Abstract

Acidification of a chelated amine sulphito complex of palladium(II) to pH <6 results in dechelation and complete loss of the co-ordinated amine ligand in the presence of an excess of sulphite; this process is completely reversible on increasing the pH(>8) and reproduces the amine sulphito complex.

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Article type: Paper
DOI: 10.1039/C39870000328
Citation: J. Chem. Soc., Chem. Commun., 1987,0, 328-330
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    Evidence for a strong labilization effect by co-ordinated sulphite in amine complexes of palladium(II)

    G. Mahal and R. van Eldik, J. Chem. Soc., Chem. Commun., 1987, 0, 328
    DOI: 10.1039/C39870000328

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