The oxidation of primary alcohols by oxo(phosphine)ruthenium(IV) complexes is shown to display a unique hydrophobic selectivity, on the basis of the dependence of the oxidation rate constant on alcohol hydrophobicity, phosphine hydrophobicity, and solvent.
M. E. Marmion and K. J. Takeuchi, J. Chem. Soc., Chem. Commun., 1987, 1396 DOI: 10.1039/C39870001396
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