Issue 18, 1987

Oxo(phosphine)ruthenium(IV) redox chemistry: substrate oxidation selectivity based on substrate hydrophobicity

Abstract

The oxidation of primary alcohols by oxo(phosphine)ruthenium(IV) complexes is shown to display a unique hydrophobic selectivity, on the basis of the dependence of the oxidation rate constant on alcohol hydrophobicity, phosphine hydrophobicity, and solvent.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1396-1397

Oxo(phosphine)ruthenium(IV) redox chemistry: substrate oxidation selectivity based on substrate hydrophobicity

M. E. Marmion and K. J. Takeuchi, J. Chem. Soc., Chem. Commun., 1987, 1396 DOI: 10.1039/C39870001396

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