(3-Nitrenophenyl)methylene (1), a non-Kekulé molecule with quintet ground state, has been generated photochemically from (3-azidophenyl)diazomethane in organic matrix at cryogenic temperatures.
H. Tukada, K. Mutai and H. Iwamura, J. Chem. Soc., Chem. Commun., 1987, 1159 DOI: 10.1039/C39870001159
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