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Photoproduct distribution spectrum of the sensitized photoreaction of 1,4-p-benzenonaphthalene

Masaru Kimura,  Katsumi Nukada,  Kyosuke Satake  and  Shiro Morosawa 

Abstract

A correlation between the type of the photoproducts of 1,4,9,10,11,12-hexahydro-1,4-p-benzeno-naphthalene (1) and triplet carbonyl and non-carbonyl sensitizers has been investigated. Electron transfer from the alkene moiety of (1) to excited sensitizers may cause the formation of naphthalene. The cage compound (2) was formed via energy transfer from excited sensitizers (Et≥ 71 kcal/mol) to the triplet state (T1) of (1). The irradiation of benzaldehyde and (1) gave the cage compound (2) and (2RS, 2aRS, 3SR, 9RS)-2a,3,8,8a,9,10,11,12-octahydro-3,8-p-benzeno-2H-naphth[2,3-b]oxete (3).

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Article type: Paper
DOI: 10.1039/P19860000885
Citation: J. Chem. Soc., Perkin Trans. 1, 1986,0, 885-888
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    Photoproduct distribution spectrum of the sensitized photoreaction of 1,4-p-benzenonaphthalene

    M. Kimura, K. Nukada, K. Satake and S. Morosawa, J. Chem. Soc., Perkin Trans. 1, 1986, 0, 885
    DOI: 10.1039/P19860000885

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