Oxidative addition of iodomethane to dimethyl(2,2′-bipyridyl)palladium(II) in acetone has resulted in isolation of the first hydrocarbylpalladium(IV) complex, fac-trimethyl(2,2′-bipyridyl)iodopalladium(IV); the complex has been structurally characterized, and reductively eliminates ethane in solution to form methyl(2,2′-bipyridyl)idodpalladium(II).
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Journal of the Chemical Society, Chemical Communications
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