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Issue 20, 1986
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Substrate-induced kinetic resolution of racemic biphosphines in situ for homogeneous catalysis

Abstract

Reaction between the resolved iridium enamide complex (+)-(3) or (–)-(3) and chiral biphosphines is highly enantioselective and permits their in situ resolution for asymmetric catalysis; the structure of (+)-(3) has been confirmed by X-ray crystallography.

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Article type: Paper
DOI: 10.1039/C39860001532
Citation: J. Chem. Soc., Chem. Commun., 1986,0, 1532-1534
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    Substrate-induced kinetic resolution of racemic biphosphines in situ for homogeneous catalysis

    N. W. Alcock, J. M. Brown and P. J. Maddox, J. Chem. Soc., Chem. Commun., 1986, 0, 1532
    DOI: 10.1039/C39860001532

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