Issue 17, 1986

A practical, efficient method for preparation of four possible stereoisomers of secondary allylic alcohols using kinetic resolution of (E)-1-trimethylsilylalk-1-en-3-ol by the sharpless process

Abstract

Kinetic resolution of (E)-1-trimethylsilylalk-1-en-3-ol by the Sharpless process, which proceeds with very large rate differences for the two isomers, combined with the reactivity of epoxysilyl compounds affords a practical, efficient method for preparation of four possible stereoisomers of secondary allylic alcohols.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1323-1325

A practical, efficient method for preparation of four possible stereoisomers of secondary allylic alcohols using kinetic resolution of (E)-1-trimethylsilylalk-1-en-3-ol by the sharpless process

Y. Kitano, T. Matsumoto and F. Sato, J. Chem. Soc., Chem. Commun., 1986, 1323 DOI: 10.1039/C39860001323

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