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Issue 23, 1986
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The oxidative addition of lodomethane to [PdMe2(bpy)] and the X-ray structure of the organopalladium(IV) product fac-[PdMe3(bpy)l](bpy = 2,2′-bipyridyl)

Abstract

Oxidative addition of iodomethane to dimethyl(2,2′-bipyridyl)palladium(II) in acetone has resulted in isolation of the first hydrocarbylpalladium(IV) complex, fac-trimethyl(2,2′-bipyridyl)iodopalladium(IV); the complex has been structurally characterized, and reductively eliminates ethane in solution to form methyl(2,2′-bipyridyl)idodpalladium(II).

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Article type: Paper
DOI: 10.1039/C39860001722
Citation: J. Chem. Soc., Chem. Commun., 1986,0, 1722-1724
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    The oxidative addition of lodomethane to [PdMe2(bpy)] and the X-ray structure of the organopalladium(IV) product fac-[PdMe3(bpy)l](bpy = 2,2′-bipyridyl)

    P. K. Byers, A. J. Canty, B. W. Skelton and A. H. White, J. Chem. Soc., Chem. Commun., 1986, 0, 1722
    DOI: 10.1039/C39860001722

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