Synthesis, properties, and 77Se nuclear magnetic resonance studies of platinum metal complexes of two isomeric tris(selenoethers), MeC(CH2SeMe)3 and Se(CH2CH2CH2SeMe)2

Eric G. Hope; William Levason; Stephen G. Murray; Gregory L. Marshall

doi:10.1039/DT9850002185

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Journal of the Chemical Society, Dalton Transactions

Issue 10, 1985

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Synthesis, properties, and ⁷⁷Se nuclear magnetic resonance studies of platinum metal complexes of two isomeric tris(selenoethers), MeC(CH₂SeMe)₃ and Se(CH₂CH₂CH₂SeMe)₂

Eric G. Hope , William Levason , Stephen G. Murray and Gregory L. Marshall

J. Chem. Soc., Dalton Trans., 1985, 2185-2190

DOI: 10.1039/DT9850002185

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Abstract
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The synthesis and properties of platinum metal complexes of MeC(CH₂SeMe)₃(tmse) and (MeSeCH₂CH₂CH₂)₂Se (bmsp), including diamagnetic [M(tmse)Cl₂](M = Pd or Pt), [M′(tmse)Cl₃](M′= Rh or Ir), [Pd(bmsp)Cl₂], [Pt(bmsp)Cl]PF₆, and [M′(bmsp)Cl₃] are described. Paramagnetic [RuLCl₃], [OsLCl₄], and [OsLCl₃](L = tmse or bmsp) are also reported. The complexes were characterised by i.r., electronic, and ¹H n.m.r. spectroscopy or magnetic measurements as appropriate. For the diamagnetic complexes, ⁷⁷Se and ¹⁹⁵Pt n.m.r. spectroscopy have been used to identify the major invertomers present. Complexes of the trithioether analogues are briefly described.

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Journal of the Chemical Society, Dalton Transactions

Synthesis, properties, and ⁷⁷Se nuclear magnetic resonance studies of platinum metal complexes of two isomeric tris(selenoethers), MeC(CH₂SeMe)₃ and Se(CH₂CH₂CH₂SeMe)₂

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