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Issue 8, 1985
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Studies on the regioselective preparation of tricarbonyl(cyclohexadienyl)iron(1+) salts

Abstract

The mixture of tricarbonyliron complexes produced from 1-methoxy-2,4-dimethylcyclohexa-1,4- diene was converted by CF3CO2H into a single product, tricarbonyl(1–5-η-2,4-dimethylcyclohexadienyl)iron hexafluorophosphate, without prior separation by chromatography. The corresponding 2-methoxy-3,5-dimethylcyclohexadienyl salt was the only complex obtained by hydride abstraction from the same mixture.

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Article type: Paper
DOI: 10.1039/DT9850001723
Citation: J. Chem. Soc., Dalton Trans., 1985,0, 1723-1725
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    Studies on the regioselective preparation of tricarbonyl(cyclohexadienyl)iron(1+) salts

    H. Curtis, B. F. G. Johnson and G. R. Stephenson, J. Chem. Soc., Dalton Trans., 1985, 0, 1723
    DOI: 10.1039/DT9850001723

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