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Issue 20, 1985
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Mixed-metal cluster compounds containing copper and/or silver atoms ligated by mono - or bi-dentate phosphines: a versatile high yield synthetic route

Scott S. D. Brown,  Ian D. Salter  and  Barry M. Smith 

Abstract

A wide variety of mixed-metal cluster compounds containing one or two copper and/or silver atoms ligated by a large selection of mono -or bi-dentate phosphines can be synthesized in very good yield (ca. 70–80%) by first treating an appropriate preformed cluster mono-or di-anion with one or two equivalents, respectively, of the complex [M(NCMe)4]PF6(M = Cu or Ag) to incorporate the coinage metal(s) into the cluster in the form of M(NCMe) moieties and then attaching the desired phosphine in situ, by a ligand exchange reaction with the labile MeCN group(s) on the generally unstable intermediate species.

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Article type: Paper
DOI: 10.1039/C39850001439
Citation: J. Chem. Soc., Chem. Commun., 1985,0, 1439-1441
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    Mixed-metal cluster compounds containing copper and/or silver atoms ligated by mono - or bi-dentate phosphines: a versatile high yield synthetic route

    S. S. D. Brown, I. D. Salter and B. M. Smith, J. Chem. Soc., Chem. Commun., 1985, 0, 1439
    DOI: 10.1039/C39850001439

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