The reaction of arylacetylenes with trimethylsilyl cyanide (1)in the presence of a palladium complex resulted in addition of (1) across the carbon–carbon triple bond with high regio- and stereo-selectivity to give β-cyano-β-arylalkenylsilanes.
N. Chatani and T. Hanafusa, J. Chem. Soc., Chem. Commun., 1985, 838 DOI: 10.1039/C39850000838
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