SCHEDULED MAINTENANCE
Ethyne reacts with [Mo2(CO)4(η-C5Me5)2] under u.v. irradiation to yield [Mo2(CO)4(µ-η1,η2-CCH2)(η-C5Me5)2], containing vinylidene bound side-on to the dimolybdenum centre as a four-electron ligand; this new species undergoes thermal isomerisation to µ-ethyne, reacts with diazomethane to give µ-allene, and is step-wise protonated to afford µ-vinyl then µ-ethylidene.
N. M. Doherty, C. Elschenbroich, H. Kneuper and S. A. R. Knox, J. Chem. Soc., Chem. Commun., 1985, 170 DOI: 10.1039/C39850000170
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...