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Issue 0, 1984
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The triethylamine catalyzed reaction of N,N-disubstituted thioamide–bromine adducts with unsubstituted thiobenzamide

Abstract

The reaction of N,N-disubstituted thioamide–bromine adducts with unsubstituted thioamide, followed by treatment with triethylamine, affords novel N′-thiobenzoylamidines along with smaller amounts of secondary products. A mechanism is proposed for the formation of the amidines. The results give an insight into the initial steps of the mechanism by which thioamides are converted into 1,2,4-thiadiazoles.

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Article type: Paper
DOI: 10.1039/P19840000897
Citation: J. Chem. Soc., Perkin Trans. 1, 1984, 897-900
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    The triethylamine catalyzed reaction of N,N-disubstituted thioamide–bromine adducts with unsubstituted thiobenzamide

    A. Corsaro, A. Compagnini, G. Perrini and G. Purrello, J. Chem. Soc., Perkin Trans. 1, 1984, 897
    DOI: 10.1039/P19840000897

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